Synthesis, Structure and Character- ization of a Novel Two-Dimensional Supramolecular Mn(II) Coordina- tion Polymer Constructed from a 1,10-Phenanthroline Derivative and a Flexible Dicarboxylate
نویسندگان
چکیده
The title complex, [Mn2(glu)(L)2(HL)2]·0.5H2O (H2glu = glutaric acid, HL = 2-(2-chloro-6-fluorophenyl)-1Himidazo[4,5-f][1,10]phenanthroline) has been synthesized using a hydrothermal method and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Crystal data: C162H88Cl8F8Mn4N32O9, triclinic, space group P1̄, a = 14.932(5), b = 16.414(5), c = 17.891(5) Å, α = 115.851(5), β = 91.288(5), γ = 112.894(5)◦ , V = 3536.4(19) Å3, Z = 1. Compound 1 exhibits 1D chains which are further stacked by C–H· · ·π interactions to give two-dimensional supramolecular layers.
منابع مشابه
Synthesis and Crystal Structure of a New Pb(II) Coordination Polymer Constructed by a 1,10-Phenanthroline Derivative and a Flexible Dicarboxylate
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